Search results for "Rayleigh scattering"
showing 10 items of 75 documents
Thermal induced conformational changes involved in the aggregation of beta-lactoglobulin
2005
Aggregation of proteins appears to be associated most often with conformational and structural changes that lead to exposure of some apolar residues. Depending on the native structure of the protein in exam, aggregation is a process that involves different mechanisms, whose time of occurrence and interplay can depend upon temperature. To single out information about the multistages of the aggregation pathway, here we investigate the thermally induced conformational and structural changes of the beta-lactoglobulin (BLG). The experimental approach consists in studying steady-state fluorescence spectra of intrinsic chromophores, two tryptophans, and Anylino-Naphthalene-Sulfonate dye (ANS) mole…
A Precise Photometric Ratio via Laser Excitation of the Sodium Layer II: Two-photon Excitation Using Lasers Detuned from 589.16 nm and 819.71 nm Reso…
2020
This article is the second in a pair of articles on the topic of the generation of a two-color artificial star (which we term a "laser photometric ratio star," or LPRS) of de-excitation light from neutral sodium atoms in the mesosphere, for use in precision telescopic measurements in astronomy and atmospheric physics, and more specifically for the calibration of measurements of dark energy using type Ia supernovae. The two techniques respectively described in both this and the previous article would each generate an LPRS with a precisely 1:1 ratio of yellow (589/590 nm) photons to near-infrared (819/820 nm) photons produced in the mesosphere. Both techniques would provide novel mechanisms f…
Rayleigh scattering of linear alkylbenzene in large liquid scintillator detectors.
2015
Rayleigh scattering poses an intrinsic limit for the transparency of organic liquid scintillators. This work focuses on the Rayleigh scattering length of linear alkylbenzene (LAB), which will be used as the solvent of the liquid scintillator in the central detector of the Jiangmen Underground Neutrino Observatory. We investigate the anisotropy of the Rayleigh scattering in LAB, showing that the resulting Rayleigh scattering length will be significantly shorter than reported before. Given the same overall light attenuation, this will result in a more efficient transmission of photons through the scintillator, increasing the amount of light collected by the photosensors and thereby the energy…
Simultaneous measurement of rotational and translational diffusion by forced Rayleigh scattering. Colloid spheres in suspension
1996
Abstract It is shown that the technique of forced Rayleigh scattering, traditionallyemployed to probe translational diffusion, can be employed to probe rotational diffusion as well. Thus with a single experiment both quantities are measured. The system under investigation is colloid spheres suspended in a glass-forming liquid. Furthermore, it is shown that the Stokes-Einstein and Debye-Stokes-Einstein relations for translational and rotational diffusion, respectively, are valid for spherical colloid particles in a supercooled liquid matrix in the vicinity of the glassy state.
Forced Rayleigh scattering from non-harmonic gratings applied to complex diffusion processes in glass-forming liquids
1999
Abstract Tracer diffusion of 9,10-phenanthrenequinone (PQ) and its photoproduct in super-cooled phenolphthalein-dimethyl-ether (PDE) was studied by forced Rayleigh scattering. In order to investigate the spatial frequency dependence of the grating dynamics, several spatial harmonics of the grating with non-sinusoidal phase profile produced by non-linear recording were monitored. An optical scheme with a diverging reading beam is proposed for simultaneous reconstruction of the harmonic components.
Rayleigh and Brillouin scattering in a lysozyme–water mixture: An unusual behavior around 343K
2011
Abstract This article describes Rayleigh and Brillouin light scattering studies on a lysozyme–water mixture from 293 K to 355 K. The scattering intensities from this system are compared with those from a sodium acetate buffer used to dissolve the lysozyme. It is found that in the vicinity of 343 K the lysozyme–water mixture becomes opalescent, and the intensity of the Brillouin peaks decreases and almost vanishes, to be restored at temperatures above 343 K. Around the same temperature the intensity of the central, unshifted Rayleigh peak, however, increases strongly. No such behavior was observed for the sodium acetate buffer. The analysis of the experimental data indicates an irreversible …
A numerical study of attraction/repulsion collective behavior models: 3D particle analyses and 1D kinetic simulations
2013
39p; International audience; We study at particle and kinetic level a collective behavior model based on three phenomena: self-propulsion, friction (Rayleigh effect) and an attractive/repulsive (Morse) potential rescaled so that the total mass of the system remains constant independently of the number of particles N . In the first part of the paper, we introduce the particle model: the agents are numbered and described by their position and velocity. We iden- tify five parameters that govern the possible asymptotic states for this system (clumps, spheres, dispersion, mills, rigid-body rotation, flocks) and perform a numerical analysis on the 3D setting. Then, in the second part of the paper…
From magnetic to nonlinear optical switches in spin-crossover complexes
2013
ISI Document Delivery No.: 109TF Times Cited: 0 Cited Reference Count: 173 Lacroix, Pascal G. Malfant, Isabelle Real, Jose-Antonio Rodriguez, Vincent Wiley-v c h verlag gmbh Weinheim Si; Various attempts to combine magnetic and nonlinear optical (NLO) properties in a molecule are reviewed, with a special focus on the possibility of interplay between the magnetic component and the quadratic (proportional to E-2) NLO response. This multidisciplinary research leads to the idea of spin-crossover-induced (SCO-induced) NLO switching and is evaluated at the synthetic level, with insights provided by computational chemistry. The need for nontraditional experimental setups to record NLO properties i…
Throughput and delay analysis of HARQ with code combining over double Rayleigh fading channels
2018
This paper proposes the use of hybrid automatic repeat request (HARQ) with code combining (HARQ-CC) to offer reliable communications over double Rayleigh channels. The double Rayleigh fading channel is of particular interest to vehicleto-vehicle communication systems as well as amplify-and-forward relaying and keyhole channels. This paper studies the performance of HARQ-CC over double Rayleigh channels from an information theoretic perspective. Analytical approximations are derived for the ϵ-outage capacity, the average number of transmissions, and the throughput of HARQ-CC. Moreover, we evaluate the delay experienced by Poisson-arriving packets for HARQ-CC. We provide analytical expression…
Two new sum-of-sinusoids-based methods for the efficient generation of multiple uncorrelated rayleigh fading waveforms
2009
Article from the journal: IEEE Transactions on Wireless Communications Publisher's version: http://dx.doi.org/10.1109/twc.2009.080769 This paper deals with the design of a set of multiple uncorrelated Rayleigh fading waveforms. The Rayleigh fading waveforms are mutually uncorrelated, but each waveform is correlated in time. The waveforms are generated by using the deterministic sum-of-sinusoids (SOS) channel modeling principle. Two new closed-form solutions are presented for the computation of the model parameters. Analytical and numerical results show that the resulting deterministic SOS-based channel simulator fulfills all main requirements imposed by the reference model with given correl…